Why is the ac in my expedition blowing hot air?

I have 2000 Ford Expedition and recently my ac stopped blowing cold air. It will blow cool air when I first start it, but then goes straight to heat. I've checked the refrigerant and its full. The compressor is also working fine. I changed the relay to see if that would help but no change. I don't know what it could be. Any thoughts?

Also the heater core went out about a month ago. But still had cold air until about a week ago. Don't know if that would be related.

Sounds like either the vent system or the heater control is not working properly. There are servo motors that open and close passages in the vents to allow for air to come from the heater, outside air, AC, etc. The reason it starts out cold is because the engine is cold. Once the engine warms up, the hot engine coolant is going through the heater core and air is probably passing through that and through the vents. It is possible that the control that allows the engine coolant to go through the heater core is stuck open. You said that the heater core went out a month ago. Do you mean that it sprung a leak and has been sealed off or something else? It sure sounds like the heater core is getting engine coolant and that the air is passing through it.

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